The grouting effect detection technology restricts the evaluation of engineering construction. This article proposes a new approach to non-destructive testing and evaluation of grouting effectiveness based on the physical parameters of cement-based grouting material modification and polarizability. By adding graphite powder to cement-based grouting materials, while ensuring the physical and mechanical properties of the materials, the polarizability is suddenly increased. By measuring the difference in polarizability, the diffusion range of the material in the underground space is delineated, thereby exploring non-destructive visual testing and evaluation of grouting effectiveness. Seven different types of cement were selected for the experiment, and a total of 140 samples were poured, demonstrating the influence of cement type and graphite powder content on the polarizability of the material；And the scientific nature of the modified material and the feasibility of non-destructive evaluation of grouting quality through induced polarization effect were verified through indoor measurement and grouting experiments, providing support for the inspection and quality evaluation of grouting filling engineering.