Unmanned aerial vehicle (UAV)-to-ground (U2G) channel models play a decisive role in the design, optimization, and evaluation of communication systems between UAV and ground terminal. This paper proposes a three-dimensional (3D) model for U2G communication channels, enhanced with ultra-wideband (UWB) features and frequency non-stationarity. This model integrates large-scale and small-scale fading components, introducing bandwidth-dependent path numbers and the UAV posture matrix for realistic scenario representation. It encompasses specific UWB U2G channel phenomena such as the channel hardening, UAV 3D movements, and posture variation effect. The channel parameters, including spatial largescale parameters (LSPs), bandwidth-correlated path numbers, delay-posture-correlated path power, and frequency-correlated path phase, are generated to capture channel non-stationary characteristics across time and frequency domains. Employing ray-tracing (RT) for the path number and optimization methods for the path delay, the proposed model ensures reliable parameter evolution. The proposed model is assessed through key statistical properties, including space-time-frequency correlation functions, power delay profile, root-mean-square delay spread, Doppler power spectrum density, and the energy variance. It is demonstrated that both posture and bandwidth variations have crucial effects on channel characteristics. The validity and practicability of this research is demonstrated by comparing the simulated outcomes with the measurement data.