Formaldehyde and Polyvinylpyrrolidone and characterized by high-end techniques is reported. MFP delves into design and modelling stoichiometric framework with dopants elucidating thermal interactions. Frameworks encompass diverse dopant structures exhibiting unique heat response by synchronizing eigenenergies with valence and conduction bands. The objective was to investigate different hysteresis assessing Frequency Resonance Energy Transfer (FRET). Thermal energy investigated structural frameworks via thermal curve. Experimentation and theoretical modelling have found effect of dopant on thermal properties through conjugative structural energies. Thermal behavior highlights intricate interplay between dopants and framework via FRET synchronizing energy to tailor dopant interactions and experimental optimizing FRET efficiency. Dynamic of dopant-framework interactions offered insights for energy transfer enhancing material performance in diverse applications. Intensified thermal studies have determined decomposition, activation energy (Ea), order of reaction, frequency factor, enthalpy change (H), entropy change (S) and Gibbs free energy (G). Thermodynamics predict stability as heating weaken cohesive forces to kinetic energy of intacting structure. From TGA/DTA, thermodynamic parameters are calculated by modern Coats – Redfern and Madhusudanan – Krishnan – Ninan equations. Calculations have elucidated HOMO-LUMO high temperature doped and coated interstities. Stability of MFP doped with metallic and graphene oxide nanoparticles as single energy ensemble gaining single valued wavefunction.