of bulk crystallization from a supersaturated solution with al- lowance for the two-step mechanism of nucleation and growth

We are happy to announce our work on MMAS special issue “Integro-differential models of natural and anthropogenic processes and phenomena” is successfully completed, so please enjoy original and high-quality contributions related to the mathematical theory of such processes and phenomena including the models, computational algorithms and analysis and mathematical methods regarded as new and promising for the understanding the problems arise both in natural and anthropogenic conditions.

This article considers the hydrodynamic problem of an oblique flow of a viscous incompressible fluid around the tip of a dendritic crystal. Approximate analytical solutions of Oseen’s hydrodynamic equations are obtained in 2D and 3D cases using special curvilinear coordinates. It is shown that the projections of the fluid velocity change significantly with a change in the flow slope and Reynolds number. The theory developed in this work has a limiting transition to the previously known solutions for the rectilinear (without tilt) fluid flow around a dendrite.

In this paper, a complete analytical solution to the integro-differential model describing the nucleation and growth of ellipsoidal crystals in a supersaturated solution is obtained. The asymptotic solution of the model equations is constructed using the saddle-point method to evaluate the Laplace-type integral. Numerical simulations carried out for physical parameters of real solutions show that the first four terms of the asymptotic series give a convergent solution. The developed theory was compared with the experimental data on desupersaturation kinetics in proteins. It is shown that the theory and experiments are in good agreement.

In this article, an approximate analytical solution of an integro-differential system of equations is constructed, which describes the process of intense boiling of a superheated liquid. The kinetic and balance equations for the bubble-size distribution function and liquid temperature are solved analytically using the Laplace transform and saddle-point methods with allowance for an arbitrary dependence of the bubble growth rate on temperature. The rate of bubble appearance therewith is considered in accordance with the Dering-Volmer and Frenkel-Zeldovich-Kagan nucleation theories. It is shown that the initial distribution function decreases with increasing the dimensionless size of bubbles and shifts to their greater values with time.

The evolution of individual crystals of ellipsoidal shape in supercooled one-component and binary melts as well as in supersaturated solutions is studied theoretically. The crystal volume growth rate is derived using the prolate ellipsoidal coordinates. We show that this rate is a function of the current crystal volume and supercooling/supersaturation of the ambient liquid. Also, we demonstrate that the particle growth rate increases with increasing the volume of ellipsoidal crystals and supercooling.

The article is concerned with the analytical solution to the integro-differential system of balance and kinetic equations that describe the crystal growth phenomenon in a binary system for various nucleation kinetics. The effect of impurity concentration on the evolutionary behavior of crystals is shown. The nonlinear dynamics of a supercooled binary melt is studied with allowance for the withdrawal mechanism of product crystals from a metastable liquid of the crystallizer.

In this paper, we study the vaporization process of a polydisperse ensemble of liquid drops on the basis of a nonlinear set of balance and kinetics equations for the particle-radius distribution function and temperature in the gaseous phase. We found an exact parametric solution to this problem using a modified time variable and the Laplace integral transform method. The distribution function of vaporizing drops as well as its moments, the temperature dynamics in gas, and the unvaporized mass of drops are found. The initial particle-radius distribution shifts to smaller particle radii with increasing the vaporization time. As this takes place, the temperature difference between the drops and gas decreases with time. It is shown that the heat of vaporization and initial total number of particles in the system substantially influence the dynamics of a polydisperse ensemble of liquid drops.

The paper deals with the analysis of stable thermo-solutal dendritic growth in the presence of intense convection. The n-fold symmetry of crystalline anisotropy as well as the two- and three-dimensional growth geometries are considered. The steady-state analytical solutions are found with allowance for the convective-type heat and mass exchange boundary conditions at the dendritic surface. A linear morphological stability analysis determining the marginal wavenumber is carried out. The new stability criterion is derived from the solvability theory and stability analysis. This selection criterion takes place in the regions of small undercooling. To describe a broader undercooling diapason, the obtained selection criterion, which describes the case of intense convection, is stitched together with the previously known selection criterion for the conductive-type boundary conditions. It is demonstrated that the stitched selection criterion well describes a broad diapason of experimental undercoolings.

In the present paper, we study the stochastically-induced behavior of a non-linear volcanic model containing three prognostic variables: the plug velocity $u$, the pressure under the plug, and the conduit volume $V$. The nouvelle phenomena of noise-induced transitions from the equilibrium to the cycle in the bistability parametric zone and noise-induced excitement with the generation of spike oscillations in the monostability zone are found in the presence of N-shaped friction force. To study these phenomena numerically, we used the computations of random solutions, the phase trajectories and time series, the statistics of interspike intervals, and the mean square variations. To study these phenomena analytically, we applied the stochastic sensitivity function technique and the confidence domains method. This approach is used to predict the noise-induced transition from a “dormant volcano” state to the “active volcano” mode. From the physical point of view, the volcano is capable to become active under the influence of external noises in the friction force, which model various compositions and properties of volcanic rocks. What is more, the volcanic plug can pop out when it is slipping heavily, and the volcano can erupt.