Md Atiqur Rahman

and 3 more

Modern engineering increasingly demands materials that offer both thermal and mechanical stability under varying conditions, while also meeting sustainability goals. Although synthetic fibres perform well, their negative environmental impact often compromises long-term sustainability. To mitigate this, researchers are turning to natural, renewable alternatives that are more environmentally friendly and recyclable. Biofibres are gaining attention in engineering applications due to their availability, low environmental carbon footprint and recyclability. Among these, the Borassus flabellifer (Palmyra palm) fruit-based fibre remains an underutilized biofibre in Bangladesh. Currently, it is primarily used for disposal or wasteto-energy purposes, despite its strong potential for high-value applications in sustainable composite materials. This review explores the potential of B. flabellifer fibre as a sustainable reinforcement for high-performance biocomposites, aiming to enhance its current value by incorporating into engineering applications. The fibre showed low density, low moisture absorption, good thermal insulation and mechanical strength, making it a feasible candidate for lightweight structural applications. Alkali treatment enhanced fibre morphology by removing hemicellulose and surface impurities, thereby improving both thermal stability and morphological property. B. flabellifer fibre-reinforced composites demonstrate improved performance comparable to conventional natural-fibre composites. These materials offer a lightweight structural solution with enhanced thermal stability, mechanical strength and vibration resistance. As a result, they present a promising and sustainable option for engineering applications, supporting global net-zero emissions targets for 2050 and aligning with broader sustainability objectives set by the UNSDGs and the Paris Agreement, while also benefiting local communities in Bangladesh.

Md Atiqur Rahman

and 3 more

Natural fibres derived from renewable resources present a sustainable and biodegradable alternative to synthetic reinforcements in polymer composites. This study evaluates the thermal and mechanical performance of Borassus husk fibre-reinforced epoxy composites, fabricated using the hand layup technique. The fibres underwent alkali treatment with 5% sodium hydroxide (NaOH) at varying durations (0.5 to 2 hours) to enhance interfacial bonding. Thermal stability and dynamic mechanical properties were assessed using thermogravimetric analysis (TGA) and dynamic mechanical analysis (DMA). Alkali treatment significantly improved the thermal stability of the composites, as demonstrated by increased char residuereaching up to 9.43%-and elevated integral process decomposition temperature (IPDT). Notably, the composite with 1-hour treated fibres exhibited the highest IPDT of 554°C. Compared to neat epoxy and composites reinforced with other natural fibres, the Borassus fibre composites demonstrated superior energy dissipation, stiffness and mechanical strength. Although the Tg decreased from 149°C in NE to a range of 122°C (0.5TBHFE) to 140°C (0.75TBHFE), the values remained competitive relative to other biofibre composites. The 0.75hour treated Borassus composite achieved the best overall performance, with an optimum storage modulus, enhanced damping behavior and minimal total mass loss-demonstrating an ideal balance among thermal stability, stiffness and damping capacity. These results highlight the potential of alkali-treated Borassus husk fiber/epoxy composites for high-performance applications, such as in the aerospace industry, while also supporting environmental sustainability and contributing to net-zero carbon emissions.

Md Atiqur Rahman

and 3 more

Natural fibres from renewable resources offer a sustainable and biodegradable alternative to synthetic reinforcements. This study investigates the thermal and mechanical properties of Borassus husk fibre/epoxy composites, fabricated via the hand layup process using 5% NaOH alkali treatment at varying durations (0.5-2 hours). Their thermal and thermo-mechanical properties were investigated through thermogravimetric analysis (TGA) and dynamic mechanical analysis (DMA) followed by outgassing test. Results indicate that alkali treatment significantly enhances the thermal stability of the composites, as evidenced by increased char content (up to 8.11%) and higher integral procedural decomposition temperature (IPDT), with the 0.75-hr treated fibre/epoxy achieving the highest IPDT (525°C). The composites also demonstrated superior energy dissipation and mechanical stiffness compared to neat epoxy (NE) and other bio-fibres based composites. The glass transition temperature (Tg) decreased from 150°C (NE) to 126°C (0.5TBHFE)-137°C (0.75TBHFE), yet outperforming composites reinforced with other conventional natural fibres. Additionally, storage modulus and damping factor (tan δ) improved significantly, with 0.5TBHFE exhibiting the best balance between stiffness and damping. The total mass loss (TML) from outgassing test was increased (0.7-0.89%) considerably compared to NE (0.26%), still confirming acceptable thermal stability. These findings suggest that alkali-treated Borassus husk fibre/epoxy composites offer excellent thermal resistance, mechanical strength and impact resistance, making them promising materials for high-performance applications in the aerospace industries, which would also promote sustainable development. However, variations in properties of biofibres require further research, along with the development of an efficient supply chain for industrial-scale production.

Md Atiqur Rahman

and 3 more

Natural fibres from renewable resources offer a sustainable and biodegradable alternative to synthetic reinforcements. This study investigates the thermal and mechanical properties of Borassus husk fibre/epoxy composites, fabricated via the hand layup process using untreated and alkali-treated fibres. The fibres were treated with 5% NaOH for varying durations (0.25-2 hours), and their thermal stability was assessed through thermogravimetric analysis (TGA) following ASTM E2550. Dynamic mechanical analysis (DMA) was performed according to ASTM D5418-01 to evaluate their mechanical performance at elevated temperatures. Results indicate that alkali treatment significantly enhances the thermal stability of the composites, as evidenced by increased char content (up to 11.5%) and higher integral procedural decomposition temperature (IPDT), with the 0.75-hr treated fibre/epoxy (0.75TBHFE) achieving the highest IPDT (580°C). The composites also demonstrated superior energy dissipation and mechanical stiffness compared to neat epoxy (NE) and other bio-fibres based composites. The glass transition temperature (Tg) increased from 83.9°C (NE) to 94.6°C (0.5TBHFE), outperforming composites reinforced with other natural fibres. Additionally, storage modulus and damping factor (tan δ) improved significantly, with 0.5TBHFE exhibiting the best balance between stiffness and damping. The total mass loss (TML) was reduced by approximately 34% compared to NE, further confirming the enhanced thermal stability. These findings suggest that alkali-treated Borassus husk fibre/epoxy composites offer excellent thermal resistance, mechanical strength and impact resistance, making them promising materials for high-performance applications in the aerospace and automotive industries, which would also promote sustainable development. However, variations in properties of biofibres require further research, along with the development of an efficient supply chain for industrialscale production.

Md Atiqur Rahman

and 3 more

This study investigates the effect of alkali treatment on the physical, thermal, flexural and thermos-mechanical properties of Borassus husk fibre-reinforced epoxy composites according to different authorized standards. Composites were fabricated using the hand layup process with untreated and alkali-treated Borassus fibres (0.25-2 hours treatment duration). The results revealed that alkali treatment significantly improved fibre-matrix adhesion, aided by scanning electron microscopic (SEM) images, leading to enhanced composite performance. The treated fibre composites exhibited lower moisture regain (0.57%-1.28%) and water absorption (0.59%-1.55%) compared to untreated composites, demonstrating improved moisture resistance. Thermal stability increased with alkali treatment, as evidenced by higher integral procedural decomposition temperature (IPDT) values, reaching 547°C for 2-hour treated fibre composites. Additionally, the glass transition temperature (Tg) improved, peaking at 94.5°C for 0.5-hour treated fibre/epoxy. Mechanical properties, including flexural modulus (up to 3.2 GPa) and strength (up to 108.7 MPa), surpassed many conventional bio-fibre composites, making these composites suitable for structural applications compared to existing conventional bio-fibres based composites. Dynamic mechanical analysis indicated superior damping properties (tanδ, up to 1.21), highlighting their enhanced energy dissipation and impact resistance. Among the treated composites, the 0.5-hour alkali-treated Borassus husk fibre/epoxy composite (0.5TBHFE) demonstrated an optimal balance between stiffness and damping, making it a promising material for aerospace and automotive applications. The study underscores the potential of Borassus husk fibres as a sustainable reinforcement alternative in high-performance composite applications. However, further optimization and industrial-scale processing strategies are required to fully harness their potential.

Md Atiqur Rahman

and 3 more

This study examines the impact of elevated temperatures on the mechanical properties of Borassus husk fibre-reinforced epoxy composites, focusing on the effects of alkali treatment (5% NaOH) on the fibres with varying treatment durations. Dynamic Mechanical Analysis (DMA) was conducted according to ASTM 5418-01 standards. The results showed that both untreated and alkali-treated fibres increased the storage modulus of the composites. The loss modulus significantly increased only for the alkali-treated composites, where the 1-hr treated fibre composite show the highest value. The glass transition temperature (Tg) of neat epoxy was 82 °C, which increased to 89 °C for composites with 0.75-hr treated fibres but decreased to 79 °C for untreated fibres. The tan δ (damping factor) also increased significantly with alkali treatment, with the highest value (1.2) observed for the 0.75-hr treated fibre composite, 33% higher than neat epoxy (0.9). Cole-Cole plots revealed improved resin-fibre adhesion for composites incorporated with 0.75 and 1 hour treated husk fibre. Phase angle data confirmed enhanced energy dissipation and viscoelastic properties in the treated fibre/epoxy composites. Furthermore, the total mass loss (TML) was the lowest for the 0.75-hr treated fibre/epoxy composite (0.4%), about 33% lower than neat epoxy, indicating better thermo-mechanical stability. Overall, alkali-treated Borassus husk fibre composites demonstrated superior mechanical stiffness, damping capacity and thermal stability compared to neat epoxy, making them promising materials for applications in aerospace and automotive industries, where performance, vibration reduction and sustainability are essential.

Md Atiqur Rahman

and 3 more

The quest for materials combining high thermal stability with environmental sustainability is intensifying in modern engineering. Synthetic fibres, while effective, often undermine sustainability goals due to their adverse environmental impact. This study explores the potential of Borassus flabellifer fruit shell (husk), typically discarded as agricultural waste in Bangladesh, as a bio-fibre alternative for thermal insulation applications. This work investigates the morphological, chemical, and thermal properties of the husk following alkali treatments with 5% sodium hydroxide (NaOH) of varying durations. The findings demonstrate that alkali treatment significantly enhances the thermal properties of Borassus husk, with observed increases in char content from 25% to 32% and Integral decomposition process temperature (IDPT) ranging from 905 to 1048 °C, which is around 12-30% higher than its untreated fibre, indicating enhanced thermal stability. Additionally, these treatments resulted in a reduction in specific heat capacity (Cp), which may be corresponded with an increase in integral process decomposition heat (IPDH). Scanning electron microscopy (SEM) analysis revealed that treated husks exhibit a rougher and cleaner surface, likely enhancing their adhesion properties in composite preparation. Fourier Transform Infrared Spectroscopy (FTIR) analysis supported these findings, showing reduced hemicellulose peaks, which align with lower moisture absorption as confirmed by thermogravimetric analysis (TGA). The optimum results were particularly observed in samples treated for 0.25 hour and 0.75 hour, indicating that Borassus husk treated with alkali for short durations could be an effective material for advanced engineering applications, which would promote eco-friendly, energy-efficient, and sustainable development.