Revealing the effect of phosphorus diffusion gettering on industrial
silicon heterojunction solar cell.
Abstract
Here we have conducted a comprehensive experimental and theoretical
investigation into the impact of the phosphorus diffusion gettering
(PDG) process on n-type industrial silicon heterojunction (SHJ) solar
cells. Our findings indicate that phosphorus penetrates deeply into the
silicon substrate as circular channels. While PDG effectively eliminates
Fe from silicon wafers, it also introduces impurities like O, P, and Cu,
which are not entirely eradicated during subsequent cleaning and
texturing processes. Optimizing the gas flow to 1000 sccm achieved a
balance between carrier lifetime and saturated dark current density in
SHJ solar cells, resulting in a 0.21% increase in average efficiency to
25.14%. Simulated analyses revealed that variations in energy loss due
to different gas flows were primarily attributed to bulk recombination
and series resistance. Our work provides valuable insights for the
application and improvement of the PDG process in industrial SHJ solar
cells.