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Revealing the effect of phosphorus diffusion gettering on industrial silicon heterojunction solar cell.
  • +9
  • D.X. Du,
  • Huanpei Huang,
  • Lin Li,
  • Chao Gao,
  • Sheng Ma,
  • Xingbing Li,
  • L. He,
  • Hongzhen Su,
  • D. Ding,
  • Zhengping Li,
  • Wenbin Zhang,
  • Wenzhong Shen
D.X. Du
Shanghai Jiao Tong University School of Physics and Astronomy
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Huanpei Huang
Shanghai Jiao Tong University School of Physics and Astronomy

Corresponding Author:haunghaunpei@sjtu.edu.cn

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Lin Li
Shanghai Jiao Tong University School of Physics and Astronomy
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Chao Gao
Shanghai Jiao Tong University School of Physics and Astronomy
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Sheng Ma
Shanghai Jiao Tong University School of Physics and Astronomy
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Xingbing Li
Guosheng Energy Research Institute
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L. He
Shanghai Jiao Tong University School of Physics and Astronomy
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Hongzhen Su
Shanghai Jiao Tong University School of Physics and Astronomy
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D. Ding
Shanghai Jiao Tong University School of Physics and Astronomy
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Zhengping Li
Shanghai Jiao Tong University School of Physics and Astronomy
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Wenbin Zhang
Guosheng Energy Research Institute
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Wenzhong Shen
Shanghai Jiao Tong University School of Physics and Astronomy
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Abstract

Here we have conducted a comprehensive experimental and theoretical investigation into the impact of the phosphorus diffusion gettering (PDG) process on n-type industrial silicon heterojunction (SHJ) solar cells. Our findings indicate that phosphorus penetrates deeply into the silicon substrate as circular channels. While PDG effectively eliminates Fe from silicon wafers, it also introduces impurities like O, P, and Cu, which are not entirely eradicated during subsequent cleaning and texturing processes. Optimizing the gas flow to 1000 sccm achieved a balance between carrier lifetime and saturated dark current density in SHJ solar cells, resulting in a 0.21% increase in average efficiency to 25.14%. Simulated analyses revealed that variations in energy loss due to different gas flows were primarily attributed to bulk recombination and series resistance. Our work provides valuable insights for the application and improvement of the PDG process in industrial SHJ solar cells.
20 Jul 2024Review(s) Completed, Editorial Evaluation Pending
20 Jul 2024Submitted to Progress in Photovoltaics
23 Jul 2024Submission Checks Completed
23 Jul 2024Assigned to Editor
15 Sep 2024Reviewer(s) Assigned