The OC in AG soils was higher than in AFG, but the OC in the PM10 was similar (between 3 and 3.3 %) (Fig. 1). The OC in RRI was higher than in RRO, but the OC in the PM10 was similar (between 1.9 and 2.2 %) (Fig. 1). The OC content in PM10 emitted by agricultural soils (AG and AFG) was between 1.3 and 1.7 higher than that emitted by rural roads (RRI and RRO). To our knowledge, this is the first report of the OC content in the PM10 emitted by rural roads. The OC contents in the PM10 emitted by rural roads is valuable information to quantify the OC losses from the soil and the OC discharges into the atmosphere by dust emission. In semiarid pampas, actual PM10 emission per unit of area of rural roads was 400 times higher than PM10 emission of agricultural soils (Ramirez Haberkon et al., 2021).
Figure 1. Contents of organic carbon (OC) in soil and in PM10. AG: agricultural soils for grain production (n=9); AFG: agricultural soils for forage and grain production (n=9); RRI: rural roads inside farm fields (n=9); RRO: rural roads outside farm fields (n=9). Different lowercase letters indicate statistical differences between land management systems (p<0.05). Bars represent standard deviations.
The OC in the PM10 was associated to the OC in the soil. This relationship was described by a quadratic function (Fig. 2), suggesting that OC was accumulated in PM10 until reaches a maximum. The maximum OC in the PM10 was 3.5 % and it was reached in soils with more than 1.3 % OC. This relationship has not been explored in previous studies for PM10, but it was explored for other soil fractions. In the clay fraction (particles <2 µm) a maximum OC content was reached when the OC in the soil was high than 3 % (Jagadamma and Lal, 2010). A limit of accumulation of OC also was found for particles fraction <20 µm (Hassink, 1997). Our results and those of previous studies suggest that the OC can be accumulated in the PM10 until a limit (saturation).