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Herein, a photocatalytic acceptorless dehydrogenative aromatization of
cyclohexanones or cyclohexenones at room temperature has been developed.
The reaction features the visible-light and cobalt co-catalyzed
sequential dehydrogenation of in-situ formed enol silyl ethers, enables
a general and straightforward method for the synthesis of a series of
phenols with diverse substitution patterns from cyclohexanones or
cyclohexenones.
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