Urban Green Spaces (UGSs) are proving to be most important part of urban area of a city. These green spaces not only provide psychological comfort to humans but also affect heat impact on city to a vast level. In a developing country like India, where urban growth is happening in a very fast and haphazard manner a little consideration is given to Green Spaces in city. Such a study has been conducted over Lucknow metro-city of Uttar Pradesh state of India. In this study, the relation between Land Use\Land Cover (LULC) and Land surface temperature (LST) has been tried to find. Using Landsat-8 OLI data (Band 3, 4 & 5) and Maximum Likelihood Classification algorithm, 6 Land Use classes are obtained, which are “Built-up”, “Vegetation”, “Shrub”, “Water”, “Fallow Land” and “Other”. In addition to these 4 Land Cover Indices namely Normalized Difference Built-up Index (NDBI), Normalized Difference Vegetation Index (NDVI), Normalized Difference Water Index (NDWI) and Normalized Difference Barren Index (NDBaI) are also generated for same areas. LST is obtained using TIRS data (Band 10 & 11) and Split Window Algorithm by Radiative Transfer Equation. Ancillary data is used for digitization of 5 assembly constituencies (ACs) of Lucknow parliamentary constituency (PC) of Lucknow district namely, Lucknow Cantonment, Lucknow North, Lucknow East, Lucknow West and Lucknow Central has been done. River and Canal passing through these areas, are also considered in Urban Green Spaces as per Urban Atlas code 14100. 250m radius buffer is generated around Built-up pixels for analysis of impact of UGSs on LST. Cantonment and East Lucknow area having highest amount of UGSs in terms of “Vegetation”, “Shrub” & “Water” pixels due to presence of Forest area in both ACs. It is found that LST is positively related with all indices except for NDVI with strong negative correlation and R2 of 0.47 and highest R2 of 0.53 with NDBI. Among all 5 ACs best correlation between all 4 LC and LST values is found in Lucknow East AC with R2 > 0.64 for NDVI, NDWI and NDBI. Lucknow East AC is having least LST but there is very little difference between LST values of Built-up pixels having minimum UGSs present in 250m radius buffer around built-ups and Built-up pixels having no UGSs around. AC Lucknow Central is having 1 °C difference in LST values of such different Built-ups.