AUTHOREA
Log in Sign Up Browse Preprints
LOG IN SIGN UP
Erik Rohloff
Erik Rohloff

Public Documents 1
Deterministic Quantum Mechanics: Classical nuclear motion explains chemical reactions...
Erik Rohloff
Dominik Rudolph

Erik Rohloff

and 3 more

October 22, 2021
Is a classical description of nuclear motion sufficient when describing chemical reactions? The present paper investigates some phenomena that were previously attributed to nuclear quantum effects. The aim is to show that these phenomena can be modelled with traditional Car-Parrinello molecular dynamics, that is, with a method which treats nuclear motion classically. We find that no additional paradigm is needed for describing chemical reactions. The special reactivity observed for carbenes can be attributed to the special environment represented by a noble gas matrix. Also the infrared spectrum of porphycene is perfectly modelled by traditional Car-Parrinello molecular dynamics. If no more convincing examples are produced, one will stick to deterministic quantum mechanics, as it is the simpler theory which, in addition, is free of paradoxa.

| Powered by Authorea.com

  • Home