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Construction of Angularly Fused Tricyclic Compounds via Photo-induced Radical Cascade Cyclization
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  • Mengqin Hu,
  • Wei Cao,
  • Yan Hao,
  • Ganxing Huang,
  • Yuqiao Zhou,
  • Song Qin,
  • Shaomin Fu,
  • Bo Liu
Mengqin Hu
Sichuan University - Wangjiang Campus
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Wei Cao
Sichuan University - Wangjiang Campus
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Yan Hao
Sichuan University - Wangjiang Campus
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Ganxing Huang
Sichuan University - Wangjiang Campus
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Yuqiao Zhou
Sichuan University - Wangjiang Campus
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Song Qin
Sichuan University - Wangjiang Campus
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Shaomin Fu
Sichuan University - Wangjiang Campus
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Bo Liu
Sichuan University - Wangjiang Campus

Corresponding Author:chembliu@scu.edu.cn

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Abstract

A photo-triggered cascade cyclization of silyl enolate to prepare angularly fused tricyclic scaffold is developed. The reaction demonstrates good substrate scope and stereo-selectivity. The excellent stereo- and regio-selectivity for this cascade reaction is elucidated via conformational analysis and DFT calculation, respectively.
27 Apr 2023Reviewer(s) Assigned
19 May 2023Review(s) Completed, Editorial Evaluation Pending
22 May 2023Editorial Decision: Revise Minor
23 May 20231st Revision Received
24 May 2023Assigned to Editor
24 May 2023Submission Checks Completed
24 May 2023Review(s) Completed, Editorial Evaluation Pending
24 May 2023Editorial Decision: Accept