Ultralong afterglow and unity quantum yield from a transparent CsCdCl3:
Mn crystal
Abstract
Transparent afterglow crystals are keenly desired for three-dimensional
information storage. Herein, CsCdCl3 perovskite crystals were grown by a
programmable cooling procedure in a hydrothermal reactor. The pristine
crystal showed an abnormal optical behavior where the absorption
increased by 2.3 folds at high temperature, leading to a 4-fold boost of
PL intensity. After Mn2+ doping, the PL QY was improved to nearly unity.
Importantly, the doped crystals exhibited an ultralong afterglow up to
12 hours after ceasing UV excitation and a high transmittance up to 75%
in the visible region. This work brought a new member to the library of
transparent afterglow crystal, opening up many possibilities to advanced
applications such as volumetric display and three-dimensional
information encryption.